Journal of Environmental Analytical Chemistry

Batch Adsorber Design for Different Solution Volume/Adsorbate Mass Ratios of Bentazon, Carbofuran and 2,4-D Adsorption on to Date Seeds Activated Carbon

Abstract

Jasim M Salman* , Falah H Hussein

The Adsorption isotherms and equilibrium of bentazon, carbofuran and 2,4-Dichlorophenoxyacetic acid (2,4-D) onto date seeds activated carbon (DSAC) were examined in batch process. Adsorption studies were conducted in the pesticides initial concentrations range of 25–250 mg/L and temperature of 30 oC. The experimental equilibrium data were analyzed by non-linear fitting using Langmuir, Freundlich and Temkin isotherm models. Equilibrium data fitted better with the Langmuir model showing maximum monolayer adsorption capacity of 78.13, 135.14 and 175.4 mg/g, for bentazon, carbofuran and 2,4-D respectively onto DSAC. A single stage batch absorber was designed for different operating line (V/M) ratios. Equilibrium data were obtained from the Langmuir isotherm at different V/M ratios using the mass balance equation for the batch absorber system. A simple linear expression relating the parameters involved in the  batchabsorber design was proposed for the studied system.